Temperature-Controlled Growth of Silicon-Based Nanostructures by Thermal Evaporation of SiO Powders
- 9 March 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry B
- Vol. 105 (13), 2507-2514
- https://doi.org/10.1021/jp004253q
Abstract
Silicon-based nanostructures with different morphologies, sizes, compositions, and microstructures were grown on Si wafers by thermal evaporation of SiO powders at 1350 °C for 5 h under 300 Torr of a flowing gas mixture of 5% H2-Ar at a flow rate of 50 standard cubic centimeters per minute (sccm). The SiO powders and Si wafers were placed inside an alumina tube, which was heated by a tube furnace. The local temperature inside the tube was carefully calibrated by a thermal couple. After evaporation, Si-containing products with different colors and appearances were formed on the surfaces of the Si wafers over a wide temperature range of 890−1320 °C and a long distance of ∼85 mm. Basing on the colors and appearances of the products, five distinct zones, which corresponding to different temperature ranges, were clearly identified from the highest temperature of 1320 °C to the lowest temperature of 890 °C. They are zone I (1250−1320 °C), zone II (1230−1250 °C), zone III (1180−1230 °C), zone IV (930−1180 °C), and zone V (890−930 °C). The deposited products were systematically studied by scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. The results show that, besides Si nanowires, many other kinds of Si-based nanostructures such as octopuslike, pinlike, tadpolelike, and chainlike structures were also formed. The temperature distribution inside the alumina tube was found to play a dominant role on the formation of these structures. It is demonstrated that a control over the growth temperature can precisely control the morphologies and intrinsic structures of the silicon-based nanomaterials. This is an important step toward design and control of nanostructures. The growth mechanisms of these products were briefly discussed.Keywords
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