Positive Homotropic Allosteric Binding of Silver(I) Cations in a Schiff Base Oligopyrrolic Macrocycle
- 10 March 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (13), 4184-4185
- https://doi.org/10.1021/ja0582004
Abstract
The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV−visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.This publication has 5 references indexed in Scilit:
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