Preparation of 1-substituted-3,3-dinitroazetidines
- 1 June 1999
- journal article
- research article
- Published by Taylor & Francis Ltd in Journal of Energetic Materials
- Vol. 17 (2-3), 233-252
- https://doi.org/10.1080/07370659908216106
Abstract
DNAZ (3,3-dinitroazetidine), 1, readily undergoes nucleophilic addition reactions with electron deficient haloaromatics, cyanogen bromide, S-methyl-N-nitroisothiourea and dichloroglyoxime to afford novel, energetic 1-substituted-3,3-dinitroazetidines. N-Nitrosation of DNAZ readily occurs, and Mannich condensations of DNAZ with poly-nitroalcohols are also described. The synthesis and properties of the energetic materials derived from these reactions will be discussed.Keywords
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