3D Porous Metal−Organic Framework Exhibiting Selective Adsorption of Water over Organic Solvents
- 27 June 2007
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 46 (15), 5835-5837
- https://doi.org/10.1021/ic7004908
Abstract
A 3D porous metal-organic framework (MOF) with 1D open channels has been constructed hydrothermally using Zn(II) and a rigid planar ligand IDC(3)- (imidazole-4,5-dicarboxylate). This MOF can adsorb water selectively over organic solvents and can be regenerated and reused. It also represents a rare example of a MOF with open channels that form/collapse reversibly upon hydration/dehydration.Keywords
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