Quantitative Determination of Total Molar Concentrations of Bioaccumulatable Organic Micropollutants in Water Using C18 Empore Disk and Molar Detection Techniques
- 1 September 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Analytical Chemistry
- Vol. 68 (17), 2916-2926
- https://doi.org/10.1021/ac951136w
Abstract
A highly sensitive and quantitative group parameter to determine total molar concentrations of organic micropollutants that can bioaccumulate in the lipid phase of aquatic organisms from effluents, surface water, and drinking water has been developed. C18 empore disk was used as a surrogate lipid phase. The partition process between water and C18 empore disk was employed to simulate the bioaccumulation process. After partition extraction of the water sample, the empore disk was extracted with cyclohexane, and total molar concentrations were determined in these extracts using vapor pressure osmometry (VPO) and gas chromatography/mass spectrometry (GC/MS), respectively. Total molar concentrations bioaccumulated in aquatic biota were estimated from the cyclohexane concentrations. Good accuracy for the total molar determination was obtained using VPO, due to the practically constant molar response factors (43.1 ± 1.7 V/M) for a wide compound range and to excellent additivity of individual compound responses. Satisfying reproducibility (0−8.3%) of VPO was obtained for sample extracts. The detection limit of VPO in cyclohexane extracts corresponded to 0.60 mM in the lipid phase of aquatic biota. A minimal separation GC/MS system was developed, which enabled highly sensitive and sufficiently accurate total molar determinations. The reproducibility of the GC/MS determination for samples ranged from 0.7 to 22%. The detection limit of GC/MS in cyclohexane extracts corresponded to 0.044 mM in the lipid phase. The determined total molar concentrations in the lipid phase of aquatic biota were in the range of 0.139−168 mM for effluents, 0.26−1.34 mM for surface water systems, and <0.044 mM for drinking water.Keywords
This publication has 27 references indexed in Scilit:
- Solid‐phase extraction of pesticides from surface water using discs, bulk sorbents and supercritical fluid extraction (SFE)Pesticide Science, 1994
- Comparison of on-line solid-phase disk extraction to liquid-liquid extraction for monitoring selected pesticides in environmental watersEnvironmental Science & Technology, 1993
- Chlorinated structural elements in high molecular weight organic matter from unpolluted waters and bleached-kraft mill effluentsEnvironmental Science & Technology, 1993
- Molecular Weight Distributions of Organic Halogens In Bleached Kraft Pulp Mill EffluentsEnvironmental Science & Technology, 1992
- Testing the performance of a VUV photoionization source on a double focussing mass spectrometer using alkanes and thiophenesInternational Journal of Mass Spectrometry and Ion Processes, 1991
- Enzymatic hydrolysis of carbohydrates in aquatic fulvic acidEnvironmental Science & Technology, 1987
- Total and partial ionization cross sections of atoms and ions by electron impactAtomic Data and Nuclear Data Tables, 1987
- Gaseous hydrocarbons around an active offshore gas and oil fieldEnvironmental Science & Technology, 1982
- Automated vapor pressure osmometer for determining the molecular weight of polymersAnalytical Chemistry, 1979
- Calibration of vapor pressure osmometers for molecular weight measurementJournal of Applied Polymer Science, 1979