N‐Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles
- 17 June 2009
- journal article
- research article
- Published by Wiley in ChemSusChem
- Vol. 2 (6), 538-541
- https://doi.org/10.1002/cssc.200800260
Abstract
Dress code: formyl. Gold nanoparticles supported on NiO catalyze the one-pot N-formylation of amines with methanol and molecular oxygen to produce formamide at a selectivity of 90 %. This process generates methyl formate in situ, followed by reaction with amines.Keywords
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