Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure
- 16 March 2017
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 139 (12), 4290-4293
- https://doi.org/10.1021/jacs.7b00261
Abstract
Tin (Sn) is known to be a good catalyst for electrochemical reduction of CO2 to formate in 0.5 M KHCO3. But when a thin layer of SnO2 is coated over Cu nanoparticles, the reduction becomes Sn-thickness dependent: the thicker (1.8 nm) shell shows Sn-like activity to generate formate whereas the thinner (0.8 nm) shell is selective to the formation of CO with the conversion Faradaic efficiency (FE) reaching 93% at −0.7 V (vs reversible hydrogen electrode (RHE)). Theoretical calculations suggest that the 0.8 nm SnO2 shell likely alloys with trace of Cu, causing the SnO2 lattice to be uniaxially compressed and favors the production of CO over formate. The report demonstrates a new strategy to tune NP catalyst selectivity for the electrochemical reduction of CO2 via the tunable core/shell structure.Keywords
Funding Information
- Ministry of Science and Technology of the People's Republic of China (2016YFB0700600)
- Army Research Office (W911NF-11-1-0353)
- Army Research Laboratory
- National Natural Science Foundation of China (21603078)
- Central People's Government of the People's Republic of China
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