K2Ag6Sn3S10: A Quaternary Sulfide Composed of Silver Sulfide Layers Pillared by Zigzag Chains [SnS3]2-
- 21 May 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 43 (13), 3764-3765
- https://doi.org/10.1021/ic035474o
Abstract
A novel framework K(2)Ag(6)Sn(3)S(10) was synthesized solvothermally and characterized by single-crystal diffraction. The framework comprises [Ag(6)SnS(4)](2+) cationic layers pillared by [SnS(3)](2)(-) zigzag chains formed by vertex-sharing SnS(4) tetrahedra, and potassium ions are located in 1D channels. This compound crystallizes in the orthorhombic Pbcn space group with a = 24.0201(2) A, b = 6.4017(3) A, c = 13.3056(4) A, Z = 4. Its thermal and optical properties are studied.This publication has 16 references indexed in Scilit:
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