Superconducting Double Perovskite Bismuth Oxide Prepared by a Low‐Temperature Hydrothermal Reaction
- 26 February 2014
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 53 (14), 3599-3603
- https://doi.org/10.1002/anie.201400607
Abstract
Perovskite‐type structures (ABO3) have received significant attention because of their crystallographic aspects and physical properties, but there has been no clear evidence of a superconductor with a double‐perovskite‐type structure, whose different elements occupy A and/or B sites in ordered ways. In this report, hydrothermal synthesis at 220 °C produced a new superconductor with an A‐site‐ordered double perovskite structure, (Na0.25K0.45)(Ba1.00)3(Bi1.00)4O12, with a maximum Tc of about 27 K.Keywords
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