High Uptakes of CO2 and CH4 in Mesoporous Metal—Organic Frameworks MIL-100 and MIL-101
Top Cited Papers
- 21 March 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Langmuir
- Vol. 24 (14), 7245-7250
- https://doi.org/10.1021/la800227x
Abstract
Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gas-solid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g(-1) or 390 cm3STP cm(-3) at 5 MPa and 303 K.Keywords
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