Thermodynamic re-assessment of the Ti–Al–Nb system
- 1 February 2009
- journal article
- Published by Walter de Gruyter GmbH in International Journal of Materials Research
- Vol. 100 (2), 218-233
- https://doi.org/10.3139/146.110015
Abstract
A CALPHAD based re-assessment of the thermodynamic description of the Ti – Al – Nb system was performed to take into account experimental evidence of the extension of the primary crystallization of the -phase to higher Al contents. The adjustable parameters of the analytic expressions of the Gibbs free energy for the Liquid, β-, β0-, δ-, σ-, γ-, α-, and 2-phases were re-optimized using available experimental data from a critical assessment of the literature. The calculated primary crystallization of -phase is in better agreement with experiment although the extension of the single phase -field to higher Al compositions could not be calculated. Calculated isothermal sections are in good agreement with experiment in the temperature range 1923 K to 1273 K.Keywords
This publication has 71 references indexed in Scilit:
- Study of the Ti-Al-Nb phase diagramPhysics of Metals and Metallography, 2006
- Thermo-Calc & DICTRA, computational tools for materials scienceCalphad, 2002
- Thermodynamic modelling of the order-disorder transformation of the orthorhombic phase of the Al-Nb-Ti systemCalphad, 2001
- Thermodynamic re-assessment of the ternary system Al-Cr-NiCalphad, 2001
- Temperature Dependence of Self-Diffusivities in B2-Type Intermetallic CompoundsHigh Temperature Materials and Processes, 1999
- High temperature deformation of NbTiAl alloys with σ + γ microstructureMaterials Science and Engineering: A, 1996
- Neutron powder diffraction study of the orthorhombic Ti2AlNb phaseScripta Metallurgica et Materialia, 1990
- Orthorhombic distortions of the α2 phase in Ti3Al-Nb alloys: Artifacts and factsScripta Metallurgica et Materialia, 1990
- Site occupation in the ordered beta phase of ternary TiAlz.sbnd;Nb alloysScripta Metallurgica, 1987
- Empirical methods of predicting and representing thermodynamic properties of ternary solution phasesCalphad, 1980