Platinum-catalyzed cross-dehydrogenative coupling reaction in the absence of oxidant
- 28 July 2010
- journal article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 8 (18), 4077-4079
- https://doi.org/10.1039/c0ob00261e
Abstract
A third strategy for cross-dehydrogenative coupling reaction has been reported via platinum-catalyzed sp3 C–H and sp3 C–H coupling reaction in the absence of oxidant. Nitroalkanes as well as dialkyl malonate derivatives, β-keto esters and malononitrile are active participants in this coupling reaction. Both cyclic and acyclic non-activated simple ketones are good reactants in this reaction.Keywords
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