Nanoscale Ru(0) Particles: Arene Hydrogenation Catalysts in Imidazolium Ionic Liquids
- 30 August 2008
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 47 (19), 8995-9001
- https://doi.org/10.1021/ic801014f
Abstract
The reduction of [Ru(COD)(2-methylallyl)2] (COD = 1,5-cyclooctadiene) dispersed in various room-temperature ionic liquids (ILs), namely, 1-n-butyl-3-methylimidazolium (BMI) and 1-n-decyl-3-methylimidazolium (DMI), associated with the N-bis(trifluoromethanesulfonyl)imidates (NTf2) and the corresponding tetrafluoroborates (BF4) with hydrogen gas (4 bar) at 50 °C leads to well-dispersed immobilized nanoparticles. Transmission electron microscopy (TEM) analysis of the particles dispersed in the ionic liquid shows the presence of [Ru(0)]n nanoparticles (Ru-NPs) of 2.1−3.5 nm in diameter. Nanoparticles with a smaller mean diameter were obtained in the ILs containing the less coordinating anion (NTf2) than that in the tetrafluoroborate analogues. The ruthenium nanoparticles in ionic liquids were used for liquid−liquid biphasic hydrogenation of arenes under mild reaction conditions (50−90 °C and 4 bar). The apparent activation energy of EA = 42.0 kJ mol−1 was estimated for the hydrogenation of toluene in the biphasic liquid−liquid system with Ru-NPs/BMI·NTf2. TEM analysis of the ionic liquid material after the hydrogenation reactions shows no significant agglomeration of the [Ru(0)]n nanoparticles. The catalyst ionic liquid phase can be reused several times without a significant loss in catalytic activity.Keywords
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