Cupric Decamolybdodivanadophosphate. A Coordination Polymer Heterogeneous Catalyst for Rapid, High Conversion, High Selectivity Sulfoxidation Using the Ambient Environment
- 18 September 2003
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 42 (21), 6610-6612
- https://doi.org/10.1021/ic0348953
Abstract
A new type of coordination network polymer involving the redox-active polyanion, PV2Mo10O405-, and bridging −CuII(OH2)4− units, {[(CuII(OH2)4)3(OH)]PV2Mo10O40}n (1), has been characterized by X-ray crystallography and several other methods. It is the first efficient heterogeneous (insoluble) catalyst for selective and rapid sulfoxidation using only the ambient environment (air at room temperature). Catalytic activity is enhanced by soluble nitrate in nontoxic perfluoropolyether (PFPE) media.Keywords
This publication has 11 references indexed in Scilit:
- Catalytic aerobic oxidation of 2-chloroethyl ethylsulfide, a mustard simulant, under ambient conditions: Effect of solvents, ligands, and transition metals on reactivityJournal of Molecular Catalysis A: Chemical, 2001
- Ag5PV2Mo10O40, a Heterogeneous Catalyst for Air-Based Selective Oxidation at Ambient TemperatureJournal of the American Chemical Society, 2001
- High Turnover Numbers for the Catalytic Selective Epoxidation of Alkenes with 1 atm of Molecular Oxygen We acknowledge T. Hayashi (The University of Tokyo), M. Wada (Nippon Shokubai Co., Ltd.), and Y. Sumita (Nippon Shokubai Co., Ltd.) for their help with experiments. This work was supported in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports and Culture of Japan.Angewandte Chemie-International Edition, 2001
- A Homogeneous Catalyst for Selective O2 Oxidation at Ambient Temperature. Diversity-Based Discovery and Mechanistic Investigation of Thioether Oxidation by the Au(III)Cl2NO3(thioether)/O2 SystemJournal of the American Chemical Society, 2001
- Homogeneous-Phase Electron-Transfer Reactions of Polyoxometalates. [(Chem. Rev. 1998, 98, 113 (this issue). Published on the Web January 22, 1998.]Chemical Reviews, 1998
- A ruthenium-substituted polyoxometalate as an inorganic dioxygenase for activation of molecular oxygenNature, 1997
- Selective Catalysis of Thioether Oxidations with Dioxygen. Critical Role of Nitrosonium EDA Complexes in the Thermal and Photochemical Transfer of Oxygen Atom from Nitrogen Oxides to Sulfur CentersThe Journal of Organic Chemistry, 1995
- Facile Catalyst Separation Without Water: Fluorous Biphase Hydroformylation of OlefinsScience, 1994
- Multicomponent Polyanions. 46. Characterization of the Isomeric Keggin Decamolybdodivanadophosphate Ions In Aqueous Solution by 31P and 51V NMRInorganic Chemistry, 1994
- The solubility of oxygen in highly fluorinated liquidsJournal of Fluorine Chemistry, 1977