Cobalt-Catalyzed Preparation of Arylindium Reagents from Aryl and Heteroaryl Bromides
- 24 August 2011
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 76 (18), 7563-7568
- https://doi.org/10.1021/jo201174r
Abstract
A cobalt–bathophenanthroline catalyst has been developed for the direct preparation of a variety of arylindium reagents from the corresponding aryl and heteroaryl bromides in the presence of indium metal and lithium chloride. The thus-formed arylindium reagents undergo efficient palladium-catalyzed cross-coupling reactions with aryl iodides, tolerating various functional groups including hydroxy and free amino groups.This publication has 45 references indexed in Scilit:
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