Remarkable decrease in overpotential of oxalate formation in electrochemical CO2reduction by a metal–sulfide cluster
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 1223-1224
- https://doi.org/10.1039/c39950001223
Abstract
Triangular metal–sulfide clusters, [{Ir(C5Me5)}3(µ3-S)2]2+ and [{Co(C5H4Me)}3(µ3-S)2]2+, catalyse the electrochemical CO2 reduction to selectively produce oxalate at –1.30 and –0.70 V (vs. Ag/AgCl), respectively, in MeCN.Keywords
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