Adenine and adenosine derivatives of rhodium acetate
- 1 January 1981
- journal article
- research article
- Published by Elsevier BV in Journal of Inorganic Biochemistry
- Vol. 14 (3), 261-265
- https://doi.org/10.1016/s0162-0134(00)80006-9
Abstract
Simple 1:1 adducts of the antitumor complex, Rh2(acetate)4, have been prepared with Adenine and Adenosine, and the binding site assigned as N7 of the purine ring. The similarity in properties between these species and those of Rh2(acetate)4/DNA solutions indicates unequivocally the same binding site for DNA and the specificity of the reaction is interpreted as due to the presence of favorable H-binding interaction between the exocyclic amino group of adenine and the hydrogen-bond acceptor acetate ligand.This publication has 9 references indexed in Scilit:
- The Mechanism of Action of Antitumor Platinum CompoundsProgress in Nucleic Acid Research and Molecular Biology, 1979
- Stereoselectivity in the binding of the bis(acetylacetonato)(nitro)cobalt(III) moiety to purines and pyrimidines and their nucleosides, interligand interactions in stereoselectivity, and the molecular and crystal structure of the bis(acetylacetonato)(nitro)(deoxyadenosine)cobalt(III) complexJournal of the American Chemical Society, 1977
- Metal‐Ion Interactions with Nucleic Acids and Nucleic Acid DerivativesPublished by Wiley ,1977
- Complexes of rhodium(II) carboxylates with adenosine 5'-mono-, 5'-di-, and 5'-triphosphatesInorganic Chemistry, 1975
- Binding sites between platinum(II) and purine or pyrimidine ribosidesInorganic Chemistry, 1974
- Tetrakis(acetato)dirhodium(II) and Similar Carboxylato CompoundsInorganic Syntheses, 1972
- Preparation and Properties of Anhydrous Rhodium-(II) Acetate and Some Adducts ThereofInorganic Chemistry, 1963
- The structure of crystalline chromous acetate revealing paired chromium atomsActa Crystallographica, 1953
- A new type of copper complex as found in the crystal structure of cupric acetate, Cu2(CH3COO)4.2H2OActa Crystallographica, 1953