Rhodium(III)‐Catalyzed Transannulation of Cyclopropenes with N‐Phenoxyacetamides through C-H Activation
- 29 September 2014
- journal article
- research article
- Published by Wiley in Angewandte Chemie
- Vol. 53 (48), 13234-13238
- https://doi.org/10.1002/anie.201408555
Abstract
An efficient rhodium(III)‐catalyzed synthesis of 2H‐chromene from N‐phenoxyacetamides and cyclopropenes has been developed. The reaction represents the first example of using cyclopropenes as a three‐carbon unit in rhodium(III)‐catalyzed C(sp2)H activations.This publication has 67 references indexed in Scilit:
- From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formationChemical Society Reviews, 2012
- Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization ReactionsAccounts of Chemical Research, 2011
- Towards mild metal-catalyzed C–H bond activationChemical Society Reviews, 2011
- C–H Functionalization in organic synthesisChemical Society Reviews, 2011
- Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen BondsChemical Reviews, 2011
- Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and ScopeChemical Reviews, 2011
- Regioselectivity of the borylation of alkanes and arenesChemical Society Reviews, 2011
- Palladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsChemical Reviews, 2010
- Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond ActivationChemical Reviews, 2009
- Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent RecoveryAccounts of Chemical Research, 2008