Polyfluoroalkyl N-(trifluoromethylsulfonyl)amidosulfites, number one stable NH-containing amidosulfites
- 1 August 2007
- journal article
- Published by Pleiades Publishing Ltd in Russian Journal of Organic Chemistry
- Vol. 43 (8), 1120-1123
- https://doi.org/10.1134/s1070428007080040
Abstract
We prepared for the first time NH-containing amidosulfites, polyfluoroalkyl N-(trifluoro-methylsulfonyl) amidosulfites CF3SO2NHS(O)ORF, by reaction of N-sulfinyl-trifluoromethanesulfonamide CF3SO2N=S=O with alcohols RFOH. Amidosulfites were formed also in reaction of chlorosulfites RFOS(O)Cl with trifluoromethanesulfonamide, with its sodium salt, and N-trimethylsilyl derivative.Keywords
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