Metal–Organic Frameworks against Toxic Chemicals
Top Cited Papers
- 24 March 2020
- journal article
- review article
- Published by American Chemical Society (ACS) in Chemical Reviews
- Vol. 120 (16), 8130-8160
- https://doi.org/10.1021/acs.chemrev.9b00828
Abstract
Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal–organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.Keywords
Funding Information
- Basic Energy Sciences (DE-FG02-08ER15967)
- Division of Graduate Education (DGE-1842165)
- Defense Threat Reduction Agency (HDTRA1-18-1-0003, HDTRA1-19-1-0007, HDTRA1-19-1-0010)
- International Institute for Nanotechnology, Northwestern University
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