Concentration dependence of the rate of diffusion-controlled reactions
- 1 June 1976
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 64 (11), 4551-4558
- https://doi.org/10.1063/1.432087
Abstract
A theory for the concentration dependence of the rate of diffusion‐controlled reactions is formulated. One of the reacting partners is taken to be a collection of static sinks. The steady state situation for a random distribution of these sinks is studied. The rate coefficient is predicted to increase with concentration of sinks and the dependence on concentration is shown to be nonanalytic.Keywords
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