Fluoride-alumina reagents: the active basic species
- 31 December 1987
- journal article
- Published by Elsevier BV in Tetrahedron Letters
- Vol. 28 (13), 1421-1424
- https://doi.org/10.1016/s0040-4039(00)95943-4
Abstract
Comparison of KF and NaF impregnated on active alumina shows that the formation of strong base by fluoride reaction with alumina cannot totally explain the extremely high reactivity of KF-alumina as a heterogeneous base for catalytic as well as non-catalytic reactions. At least three mechanisms apparently give rise to the high basicity.Keywords
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