Chemically modified smectites
Open Access
- 1 March 2003
- journal article
- Published by Mineralogical Society in Clay Minerals
- Vol. 38 (1), 127-138
- https://doi.org/10.1180/0009855033810083
Abstract
This paper summarizes recent results obtained on chemical modifications of smectites. These include replacement of exchangeable cations with protons, a process connected with smectite autotransformation – attack of protons on the layers and liberation of central atoms from the octahedral and tetrahedral sheets, causing modification of the acid sites on the particles. More severe modifications occur during dissolution in inorganic acids, when the layers are dissolved and threedimensional amorphous silica is formed. The negative charge on the smectite layers can be increased via reduction of structural Fe(III) to Fe(II) or decreased via fixation of small exchangeable cations, such as Li+, upon treatment at elevated temperatures. Heating for 24 h at different temperatures between 100 and 300ºC leads to a series of chemically similar materials of different charge, prepared from the same parent mineral. Such series are suitable for investigation of the effect of the layer charge on selected properties of smectites. Fe(II) can be partly stabilized in reduced smectites by Li fixation upon heating.Keywords
This publication has 49 references indexed in Scilit:
- Effects of chemical composition and temperature of heating on the infrared spectra of Li-saturated dioctahedral smectites. (I) Mid-infrared regionClay Minerals, 2000
- Effects of chemical composition and temperature of heating on the infrared spectra of Li-saturated dioctahedral smectites. (II) Near-infrared regionClay Minerals, 2000
- Reduction of Fe(III) in griffithiteClay Minerals, 2000
- FTIR spectroscopic characterization of thermally treated Cu2+, Cd2+, and Li+ montmorillonitesSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 1999
- Partial Stabilization of Fe(II) in Reduced Ferruginous Smectite by Li FixationClays and Clay Minerals, 1999
- Acid-Treated Montmorillonites—A Study by 29Si and 27Al MAS NMRClay Minerals, 1994
- Reduction and Reoxidation of Nontronite: Extent of Reduction and Reaction RatesClays and Clay Minerals, 1990
- The Swelling of Clay: II. MontmorillonitesSoil Science Society of America Journal, 1980
- Geology of Bleaching EarthsPublished by Elsevier BV ,1968
- Chemical Determination of Tetrahedral Ions in Nontronite and MontmorilloniteClays and clay minerals (National Conference on Clays and Clay Minerals), 1953