Reaction of Carbon Dioxide with 1-Phenylaziridine Catalyzed by Organo-antimony and -tin Compounds
- 1 September 1985
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 58 (9), 2717-2718
- https://doi.org/10.1246/bcsj.58.2717
Abstract
The reactions of carbon dioxide(CO2) with 1-phenylaziridine(1) to afford 3-phenyl-2-oxazolidone(2) were carried out in the presence of organo-antimony and -tin compounds as catalysts. Tetraphenylstibonium bromide(Ph4SbBr) and triphenyltin bromide(Ph3SnBr) were found to be active catalysts. The use of a polar aprotic solvent, such as a HMPA, provided optimal reaction conditions.Keywords
This publication has 9 references indexed in Scilit:
- Direct Synthesis of Cyclic Carbonates in the Presence of Organometallic Compounds. Catalyses by Systems from IVA, VA, and VIA Group Compounds and Lewis BaseBulletin of the Chemical Society of Japan, 1982
- Synthesis of cyclic carbonates from carbon dioxide and epoxides in the presence of organoantimony compounds as novel catalystsThe Journal of Organic Chemistry, 1980
- Preparation, properties and structure of poly(triphenylstibine oxideJournal of Organometallic Chemistry, 1972
- 2-OxazolidonesChemical Reviews, 1967
- Gas Chromatography of Organotin CompoundsThe Journal of the Society of Chemical Industry, Japan, 1960
- The Synthesis and Polymerization of N-Phenylethylenimine and the Synthesis of N,N'-DiphenylpiperazineJournal of the American Chemical Society, 1954
- Tetraphenylphosphonium and Tetraphenylstibonium ChlorideJournal of the American Chemical Society, 1948
- N-β-Bromoethylaniline HydrobromideJournal of the American Chemical Society, 1948
- Darstellung von Trialkyl‐Stibinen,‐Arsinen und ‐Phosphinen mittels Grignard's ReactionEuropean Journal of Inorganic Chemistry, 1906