From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities
- 26 March 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (38), 3961-3963
- https://doi.org/10.1039/c3cc41382a
Abstract
Transformation of tetra(4-cyanophenyl)ethylene under Lewis acidic (ZnCl2) conditions at 400 °C leads to the formation of a porous covalent triazine-based organic framework (CTF) with a high surface area (2235 m2 g−1), high CO2 and CH4 uptakes and the highest hydrogen uptake for a CTF material (1.86 wt% at 77 K, 1 bar).Keywords
This publication has 25 references indexed in Scilit:
- Development of organic porous materials through Schiff-base chemistryCrystEngComm, 2012
- Porous covalent–organic materials: synthesis, clean energy application and designJournal of Materials Chemistry A, 2012
- Covalent organic frameworks (COFs): from design to applicationsChemical Society Reviews, 2012
- Synthesis and Characterization of Porous Benzimidazole-Linked Polymers and Their Performance in Small Gas Storage and Selective UptakeChemistry of Materials, 2012
- Nanoporous organic polymer networksProgress in Polymer Science, 2011
- Porous Organic Polymers in Catalysis: Opportunities and ChallengesACS Catalysis, 2011
- Exploitation of Intrinsic Microporosity in Polymer-Based MaterialsMacromolecules, 2010
- Nanoporous Polymers for Hydrogen StorageSmall, 2009
- High Surface Area Nanoporous Polymers for Reversible Hydrogen StorageChemistry of Materials, 2006
- Poly(aryleneethynylene)s: Syntheses, Properties, Structures, and ApplicationsChemical Reviews, 2000