1,3-Diphenyl-5-(9-phenanthryl)-4,5-dihydro-1H-pyrazole (DPPhP): structure, properties, and application in organic light-emitting diodes
- 5 November 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 12 (12), 3481-3486
- https://doi.org/10.1039/b208130j
Abstract
A novel hole-transport material, 1,3-diphenyl-5-(9-phenanthryl)-4,5-dihydro-1H-pyrazole (DPPhP), was synthesized and fully characterized. The crystal structure of DPPhP was determined by X-ray diffraction analyses. DSC and AFM analysis demonstrate that DPPhP has a high Tg of 96 °C and good film forming ability. The hole-transport performance of DPPhP was examined by fabricating a multilayer device with structure of ITO/DPPhP (60 nm)/AlQ (60 nm)/LiF (0.8 nm)/Al, using DPPhP as the hole-transport layer along with an emitting-material, tris-(8-hydroxyquinolino)aluminium (AlQ). Both the brightness and efficiency of the device are about 30% higher than those of the device using N,N′-di-1-naphthenyl-N,N′-diphenyl-1,1′-biphenyl-4,4′-diamine (α-NPD) as the hole-transport layer.Keywords
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