Dinuclear Palladium Complexes—Precursors or Catalysts?
- 11 September 2012
- journal article
- highlight
- Published by Wiley in Angewandte Chemie
- Vol. 51 (42), 10448-10450
- https://doi.org/10.1002/anie.201205417
Abstract
Calculations help: Recent work from Schoenebeck's group has demonstrated beyond reasonable doubt that the dimeric LPdIBr catalysts that are widely used in coupling chemistry operate through prior formal reduction to an LPd0 species. Conversely, L2Pd0 catalysts can be activated by oxidation. In other cases a binuclear species can persist through the catalytic cycle.This publication has 21 references indexed in Scilit:
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