High-valent oxo-molybdenum and oxo-rhenium complexes as efficient catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions
- 11 July 2012
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Chemical Society Reviews
- Vol. 41 (17), 5641-5653
- https://doi.org/10.1039/c2cs35155b
Abstract
High-valent oxo-complexes have recently emerged as powerful catalysts for the activation of X–H (X = Si, B, P and H) bonds and for the reduction of several functional groups. This new reactivity represents a complete reversal from the traditional role of these complexes as oxidation catalysts and opened a new research area for high-valent oxo-complexes. This tutorial review highlights the work developed using high-valent oxo-molybdenum and oxo-rhenium complexes as excellent catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions.Keywords
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