Superconductivity in fullerides

Abstract

Experimental studies of the superconductive properties of fullerides are briefly reviewed. Theoretical calculations of the electron-phonon coupling, in particular for the intramolecular phonons, are discussed extensively. The calculations are compared with coupling constants deduced from a number of different experimental techniques. It is discussed why ${\mathrm{A}}_3$ ${\mathrm{C}}_{60}$ are not Mott-Hubbard insulators, in spite of the large Coulomb interaction. Estimates of the Coulomb pseudopotential ${\mathrm{\mu }}^{\mathrm{*}}$, describing the effect of the Coulomb repulsion on the superconductivity, as well as possible electronic mechanisms for the superconductivity, are reviewed. The calculation of various properties within the Migdal-Eliashberg theory and attempts to go beyond this theory are described.