Mass Spectrometry at High Temperatures. XVIII. The Stabilities of the Mono- and Difluorides of Scandium and Yttrium
- 1 November 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (9), 3122-3125
- https://doi.org/10.1063/1.1712362
Abstract
Mono‐, di‐, and trifluorides of Sc and Y have been identified in the vapors over mixtures of the corresponding metals and CaF2 in Ta‐Knudsen cells at high temperatures. Equilibria among these molecules and Ca and CaF have been studied by a mass spectrometer and their dissociation energies have been determined.Keywords
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