Luminescent MTN-Type Cluster–Organic Framework with 2.6 nm Cages
- 15 October 2012
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 134 (43), 17881-17884
- https://doi.org/10.1021/ja308801n
Abstract
From a basic tetrahedral Cu4I4 cluster, a new MTN-type cluster–organic framework (COZ-1) containing giant 64512 and 512 cages was successfully constructed. The 64512 cage has an inner diameter of 2.6 nm and a large pore volume of 9.2 nm3; these tetrahedral Cu4I4 clusters with bulky size offer new opportunities for not only the formation of 4-connected zeotype structures but also the integration of porosity and photoluminescent properties from both the cluster and the framework.Keywords
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