Fine Structure of the Hydrogen Atom. Part I

Abstract

The fine structure of the hydrogen atom is studied by a microwave method. A beam of atoms in the metastable $2{}_{}{}^2{}_{}{}^{}S_{\frac{1}{2}}^{}{}_{}{}^{}$ state is produced by bombarding atomic hydrogen. The metastable atoms are detected when they fall on a metal surface and eject electrons. If the metastable atoms are subjected to radiofrequency power of the proper frequency, they undergo transitions to the non-metastable states $2{}_{}{}^2{}_{}{}^{}P_{\frac{1}{2}}^{}{}_{}{}^{}$ and $2{}_{}{}^2{}_{}{}^{}P_{\frac{3}{2}}^{}{}_{}{}^{}$ and decay to the ground state $1{}_{}{}^2{}_{}{}^{}S_{\frac{1}{2}}^{}{}_{}{}^{}$ in which they are not detected. In this way it is determined that contrary to the predictions of the Dirac theory, the $2{}_{}{}^2{}_{}{}^{}S_{\frac{1}{2}}^{}{}_{}{}^{}$ state does not have the same energy as the $2{}_{}{}^2{}_{}{}^{}P_{\frac{1}{2}}^{}{}_{}{}^{}$ state, but lies higher by an amount corresponding to a frequency of about 1000 Mc/sec. Within the accuracy of the measurements, the separation of the $2{}_{}{}^2{}_{}{}^{}P_{\frac{1}{2}}^{}{}_{}{}^{}$ and $2{}_{}{}^2{}_{}{}^{}P_{\frac{3}{2}}^{}{}_{}{}^{}$ levels is in agreement with the Dirac theory. No differences in either level shift or doublet separation were observed between hydrogen and deuterium. These results were obtained with the first working apparatus. Much more accurate measurements will be reported in subsequent papers as well as a detailed comparison with the quantum electrodynamic explanation of the level shift by Bethe.