Hierarchical Porous O‐Doped g‐C3N4 with Enhanced Photocatalytic CO2 Reduction Activity
Top Cited Papers
- 3 February 2017
- Vol. 13 (15)
- https://doi.org/10.1002/smll.201603938
Abstract
Artificial photosynthesis of hydrocarbon fuels by utilizing solar energy and CO2 is considered as a potential route for solving ever-increasing energy crisis and greenhouse effect. Herein, hierarchical porous O-doped graphitic carbon nitride (g-C3N4) nanotubes (OCN-Tube) are prepared via successive thermal oxidation exfoliation and curling-condensation of bulk g-C3N4. The as-prepared OCN-Tube exhibits hierarchically porous structures, which consist of interconnected multiwalled nanotubes with uniform diameters of 20–30 nm. The hierarchical OCN-Tube shows excellent photocatalytic CO2 reduction performance under visible light, with methanol evolution rate of 0.88 µmol g−1 h−1, which is five times higher than bulk g-C3N4 (0.17 µmol g−1 h−1). The enhanced photocatalytic activity of OCN-Tube is ascribed to the hierarchical nanotube structure and O-doping effect. The hierarchical nanotube structure endows OCN-Tube with higher specific surface area, greater light utilization efficiency, and improved molecular diffusion kinetics, due to the more exposed active edges and multiple light reflection/scattering channels. The O-doping optimizes the band structure of g-C3N4, resulting in narrower bandgap, greater CO2 affinity, and uptake capacity as well as higher separation efficiency of photogenerated charge carriers. This work provides a novel strategy to design hierarchical g-C3N4 nanostructures, which can be used as promising photocatalyst for solar energy conversion.Keywords
Funding Information
- National Natural Science Foundation of China (51320105001, 51372190, 21573170, 51272199, 21433007)
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