Aerobic Oxidative Amination of Unactivated Alkenes Catalyzed by Palladium
- 11 February 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (9), 2868-2869
- https://doi.org/10.1021/ja0433020
Abstract
The first examples of palladium-catalyzed oxidative amination of unactivated alkyl olefins have been identified. To be successful, these reactions must be conducted under cocatalyst-free conditions that involve direct dioxygen-coupled turnover of the palladium catalyst. The oxidative amination products of norbornene and other cyclic alkenes implicate a cis-aminopalladation mechanism.Keywords
This publication has 11 references indexed in Scilit:
- Catalytic Hydroamination of Alkynes and Norbornene with Neutral and Cationic Tantalum Imido ComplexesOrganic Letters, 2004
- TiCl4-Catalyzed Intermolecular Hydroamination Reactions of NorborneneOrganic Letters, 2004
- Dioxygen-Coupled Oxidative Amination of StyreneJournal of the American Chemical Society, 2003
- Catalytic intermolecular hydroamination of alkenes: Beneficial effect of ionic solventsJournal of Molecular Catalysis A: Chemical, 2003
- The [IrCl(Diphosphine)]2/Fluoride System. Developing Catalytic Asymmetric Olefin HydroaminationJournal of the American Chemical Society, 1997
- Addition of ethyl urethane to olefins: A new approach to the synthesis of aliphatic carbamatesJournal of Molecular Catalysis A: Chemical, 1996
- Palladium(II)-catalyzed amidation of alkenesTetrahedron Letters, 1992
- Rational design in homogeneous catalysis. Iridium(I)-catalyzed addition of aniline to norbornylene via nitrogen-hydrogen activationJournal of the American Chemical Society, 1988
- Reaction of carbon disulfide with trinuclear palladium and platinum clusters. Crystal structure of Pt2(.mu.-CS2)2(P(tert-Bu)2Ph)2Inorganic Chemistry, 1984
- The isomerization of olefins by palladium complexesJournal of Catalysis, 1965