The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation
- 9 March 2011
- journal article
- Published by Pleiades Publishing Ltd in High Energy Chemistry
- Vol. 45 (2), 99-103
- https://doi.org/10.1134/s0018143911020147
Abstract
The features of nanoparticle formation by the radiation-chemical reduction of Cu2+ ions in polyacrylic acid-polyethyleneimine complexes have been studied. It has been shown that the swollen film/aqueous alcohol medium interphase exchange of the reducing species and the specifics of X-ray energy transfer play an important role in the formation of metal particles in the subsurface layer of polymer matrixes. An analysis of EPR and X-ray diffraction data shows that an acetaldehyde admixture increases the Cu2+ reduction rate of and enables the growth of nanoparticles.Keywords
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