Microemulsion Systems for Fiber Deconstruction into Cellulose Nanofibrils
- 15 December 2014
- journal article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 6 (24), 22622-22627
- https://doi.org/10.1021/am5067332
Abstract
A new method to produce cellulose nanofibrils (CNF) is proposed to reduce the energy demand during deconstruction of precursor fibers suspended in aqueous media. Microemulsions were formulated with aqueous solutions of urea or ethylenediamine and applied to disrupt interfibril hydrogen bonding. Compared to typical fibrillation of lignin-containing and lignin-free fibers, pretreatment with microemulsion systems allowed energy savings during microfluidization of 55 and 32%, respectively. Moreover, microemulsion processing facilitated smaller-scale CNF structures (higher degrees of deconstruction), with higher water retention value (WRV) and surface area. Urea-containing microemulsions were found to be most effective in reducing energy consumption and in weakening the cellulosic matrix. Films prepared from CNF processed after pretreatment with urea-containing microemulsions presented a more uniform fiber network and produced films with smoother surfaces compared to those based on ethylenediamine. The lignin-containing CNF (LCNF) produced denser films than those obtained from lignin-free CNF. The mechanical properties of films obtained after application of microemulsion pretreatment were compared, and the benefits of the proposed approach were further confirmed. Overall, fiber deconstruction after microemulsion treatment is a step toward energy-efficient production of nanocellulose.Keywords
Funding Information
- U.S. Department of Energy
- U.S. Department of Transportation
- U.S. Department of Agriculture
- Suomen Akatemia
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