Microwave-assisted syntheses of highly CO2-selective organic cage frameworks (OCFs)
- 12 December 2011
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 3 (3), 874-877
- https://doi.org/10.1039/c1sc00589h
Abstract
A series of organic cage frameworks (OCFs) were successfully synthesized through microwave-assisted Sonogashira coupling of 3-D molecular cage building blocks with various diacetylene linkers. These novel framework materials exhibited unprecedented, high ideal selectivity (up to 213/1) in adsorption of CO2 over N2 under ambient conditions.This publication has 29 references indexed in Scilit:
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