A One-Pot, Single-Solvent Process for Tandem, Catalyzed C-H Borylation-Suzuki-Miyaura Cross-Coupling Sequences

12 December 2008

journal article
cluster
Published by Georg Thieme Verlag KG in Synlett

Vol. 2009 (01), 147-150
https://doi.org/10.1055/s-0028-1087374

Abstract

Methyl tert-butyl ether is a suitable solvent for iridium-catalyzed C-H borylation followed, in the same pot, by palladium-catalyzed Suzuki-Miyaura cross-coupling sequences, giving high yields of biaryls.

Keywords

BIARYLS
CROSS-COUPLING
HOMOGENEOUS CATALYSIS
BORONATE ESTER
TANDEM REACTIONS

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