Thermosensitive gating effect and selective gas adsorption in a porous coordination nanocage
- 2 September 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 46 (39), 7352-7354
- https://doi.org/10.1039/c0cc02771e
Abstract
A porous coordination nanocage functionalized with 24 triisopropylsilyl groups exhibits a remarkable thermosensitive gate opening phenomenon and demonstrates a molecular sieving effect at a certain temperature range, which can be used for gas separation purposes.Keywords
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