A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane
- 8 December 2011
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 48 (8), 1180-1182
- https://doi.org/10.1039/c1cc15864c
Abstract
A new type of supported rhodium nanoparticles were reproducibly prepared from N2H4BH3 reduction of [Rh(μ-Cl)(1,5-cod)]2 without using any solid support and pre-treatment technique. Their characterization shows the formation of well dispersed rhodium(0) nanoparticles within the framework of a polyaminoborane based polymeric support. These new rhodium(0) nanoparticles were found to be the most active supported catalyst in the catalytic dehydrogenation of ammonia-borane in water at room temperature.Keywords
This publication has 39 references indexed in Scilit:
- Zeolite framework stabilized nickel(0) nanoparticles: Active and long-lived catalyst for hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydrideCatalysis Today, 2011
- Osmium(0) nanoclusters stabilized by zeolite framework; highly active catalyst in the aerobic oxidation of alcohols under mild conditionsDalton Transactions, 2010
- Ruthenium(0) Nanoclusters Stabilized by a Nanozeolite Framework: Isolable, Reusable, and Green Catalyst for the Hydrogenation of Neat Aromatics under Mild Conditions with the Unprecedented Catalytic Activity and LifetimeJournal of the American Chemical Society, 2010
- Zeolite confined nanostructured dinuclear ruthenium clusters: preparation, characterization and catalytic properties in the aerobic oxidation of alcohols under mild conditionsJournal of Materials Chemistry, 2009
- Preparation and characterization of zeolite framework stabilized cuprous oxide nanoparticlesMaterials Letters, 2009
- Catalytic dehydrogenation of ammonia borane in non-aqueous mediumInternational Journal of Hydrogen Energy, 2009
- A novel, simple, organic free preparation and characterization of water dispersible photoluminescent Cu2O nanocubesMaterials Letters, 2009
- Base Metal Catalyzed Dehydrogenation of Ammonia−Borane for Chemical Hydrogen StorageJournal of the American Chemical Society, 2007
- Cryochemical preparation of monomeric aminoboraneInorganic Chemistry, 1970
- Core-electron binding energies for compounds of boron, carbon, and chromiumInorganic Chemistry, 1970