Activation of molecular oxygen by S-radicals: experimental and computational studies on a novel oxidation of alkynes to α-diketones
- 16 October 2008
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 46,p. 6239-6241
- https://doi.org/10.1039/b815358b
Abstract
Thiylperoxyl radicals 14 are the suggested reactive key-intermediates in the oxidation of bis-aromatic alkynes to α-diketones using molecular oxygen “activated” by thiyl radicals.Keywords
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