Synthesis of phenanthridinones viapalladium-catalyzed C(sp2)–H aminocarbonylation of unprotected o-arylanilines
- 1 January 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (2), 173-175
- https://doi.org/10.1039/c2cc36817j
Abstract
An efficient synthesis of free (NH)-phenanthridinones through Pd-catalyzed C(sp2)–H aminocarbonylation of unprotected o-arylanilines under an atmospheric pressure of CO has been developed. Some ortho heteroarene substituted anilines as well as N-alkyl protected o-arylanilines are also suitable substrates for this C–H aminocarbonylation reaction.Keywords
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