Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization
Top Cited Papers
- 16 April 2012
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 134 (17), 7305-7308
- https://doi.org/10.1021/ja302278s
Abstract
A Pd-catalyzed asymmetric synthesis of Si-stereogenic dibenzosiloles is developed through enantioselective C–H bond functionalization of prochiral 2-(arylsilyl)aryl triflates. High chemo- and enantioselectivities are achieved by employing a Josiphos-type ligand under mild conditions.Keywords
This publication has 88 references indexed in Scilit:
- Silicon Analogues of Polyfluorene as Materials for Organic ElectronicsAustralian Journal of Chemistry, 2009
- High-efficiency red and green light-emitting polymers based on a novel wide bandgap poly(2,7-silafluorene)Journal of Materials Chemistry, 2008
- Silole‐Containing Polymers: Chemistry and Optoelectronic PropertiesMacromolecular Rapid Communications, 2007
- Fluorene and silafluorene conjugated copolymer: A new blue light-emitting polymerSynthetic Metals, 2006
- Poly(3,6-silafluorene-co-2,7-fluorene)-based high-efficiency and color-pure blue light-emitting polymers with extremely narrow band-width and high spectral stabilityJournal of Materials Chemistry, 2006
- High-efficiency blue light-emitting electrophosphorescent device with conjugated polymers as the hostApplied Physics Letters, 2006
- Poly(9,9-dialkyl-3,6-dibenzosilole)—a high energy gap host for phosphorescent light emitting devicesChemical Communications, 2005
- Hole transport triphenylamine–spirosilabifluorene alternating copolymer: synthesis and optical, electrochemical and electroluminescent propertiesPolymer, 2005
- Highly Fluorescent Solid-State Asymmetric Spirosilabifluorene DerivativesJournal of the American Chemical Society, 2005
- Poly(2,7-dibenzosilole): A Blue Light Emitting PolymerJournal of the American Chemical Society, 2005