Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation
- 20 November 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 130 (50), 16828-16829
- https://doi.org/10.1021/ja804014y
Abstract
Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.Keywords
This publication has 29 references indexed in Scilit:
- Solution-Phase Structural Characterization of Supramolecular Assemblies by Molecular DiffractionJournal of the American Chemical Society, 2007
- Pseudo‐Allosteric Recognition of Mandelic Acid with an Enantioselective Coordination ComplexAngewandte Chemie-International Edition, 2006
- X-ray Diffraction and DOSY NMR Characterization of Self-Assembled Supramolecular Metallocyclic Species in SolutionJournal of the American Chemical Society, 2005
- Asymmetric Induction during Yang Cyclization of α-Oxoamides: The Power of a Covalently Linked Chiral Auxiliary Is Enhanced in the Crystalline StateJournal of the American Chemical Society, 2005
- Coordination Assemblies from a Pd(II)-Cornered Square ComplexAccounts of Chemical Research, 2005
- Structural Characterization of Modular Supramolecular Architectures in SolutionJournal of the American Chemical Society, 2004
- Alkane Oxidation via Photochemical Excitation of a Self-Assembled Molecular CageJournal of the American Chemical Society, 2004
- Au-colloid–‘molecular square’ superstructures: novel electrochemical sensing interfacesChemical Communications, 1999
- A conjugated triple strand porphyrin arrayChemical Communications, 1999
- Tetraacetylethane Dianion (Tae) As a Bridging Ligand for Molecular Square Complexes: CoII4(Tae)4(Dpa)4, Dpa = Di-2-pyridylamine, a Chiral Molecular Square in the Solid StateJournal of the American Chemical Society, 1998