First-principles modeling of resistance switching in perovskite oxide material

Abstract
We report a first-principles study on Sr Ru O 3 ∕ Sr Ti O 3 interface in the presence of the oxygen vacancy. While the oxygen vacancy on the side of Sr Ti O 3 significantly lowers the Schottky barrier height, the oxygen vacancy close to the interface or inside the metallic electrode results in a Schottky barrier comparable to that of the clean interface. Based on these results, we propose a model for resistance-switching phenomena in perovskite oxide∕metal interfaces where electromigration of the oxygen vacancy plays a key role. Our model provides a consistent explanation of a recent experiment on resistance switching in Sr Ru O 3 ∕ Nb : Sr Ti O 3 interface.