Adsorption of Metallic Cations on Silica Gel-Immobilized 8-Hydroxyquinoline
- 10 January 2000
- journal article
- Published by Taylor & Francis Ltd in Separation Science and Technology
- Vol. 35 (10), 1661-1679
- https://doi.org/10.1081/ss-100100247
Abstract
TLC-grade silica gel was functionalized with 8-hydroxyquinoline via a catalyzed Mannich amminomethylation reaction. The resulting solid was characterized by FT-IR and used as a sorbent for 0.05–5 mmol·L−1 Cu(II), Cd(II), Zn(II), Pb(II), and Fe(III) from aqueous solutions in the batch mode. Experiments were carried out in both single and multiple cation solutions. The influence of the aqueous media composition on the adsorption process, the possible adsorbed species, and the adsorption kinetics are discussed. Overall equilibrium constants for these processes are reported.Keywords
This publication has 14 references indexed in Scilit:
- UPTAKE OF METAL IONS BY A NEW CHELATING ION-EXCHANGE RESIN. PART 5 : THE EFFECT OF SOLUTION MATRIX ON ACTINIDESSolvent Extraction and Ion Exchange, 1994
- Synthesis, properties and applications of silica-immobilized 8-quinolinol: Part 2. On-line column preconcentration of copper, nickel and cadmium from sea water and determination by inductively-coupled plasma atomic emission spectrometryAnalytica Chimica Acta, 1994
- Synthesis, properties and applications of silica-immobilized 8-quinolinol: Part 1. Characterization of silica-immobilized 8-quinolinol synthesized via a Mannich reactionAnalytica Chimica Acta, 1994
- Separation of noble metal ions on silica with chemically bonded ligandsMicrochimica Acta, 1994
- Determination of trace levels of metal ions in water samples by inductively coupled plasma mass spectrometry after on-line preconcentration on SO3-oxine CM-celluloseAnalytical and Bioanalytical Chemistry, 1993
- On-line preconcentration of aluminium, gallium and indium with quinolin-8-ol for determination by atomic absorption spectrometryJournal of Analytical Atomic Spectrometry, 1993
- Calcium sorption by immobilized oxine and its use in determining free calcium ion concentration in aqueous solutionAnalytical Chemistry, 1988
- Solid-liquid extraction and back extraction of metals with silica-immobilized 8-hydroxyquinolineAnalytical and Bioanalytical Chemistry, 1988
- Synthesis of silica-immobilized 8-quinolinol with (aminophenyl)trimethoxysilaneAnalytical Chemistry, 1983
- Silica gel as an insoluble carrier for the preparation of selective chromatographic adsorbents : The preparation of 8-hydroxyquinonline substituted silica gel for the chelation chromatography of some trace metalsJournal of Chromatography A, 1973