Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
Top Cited Papers
- 11 September 2015
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 349 (6253), 1208-1213
- https://doi.org/10.1126/science.aac8343
Abstract
Improving cobalt catalysts: Tethering molecular catalysts together is a tried and trusted method for making them easier to purify and reuse. Lin et al. now show that the assembly of a covalent organic framework (COF) structure can also improve fundamental catalytic performance. They used cobalt porphyrin complexes as building blocks for a COF. The resulting material showed greatly enhanced activity for the aqueous electrochemical reduction of CO 2 to CO. Science , this issue p. 1208Keywords
Funding Information
- U.S. Department of Energy
- Lawrence Berkeley National Laboratory (101528-002)
- DOE, Office of Science, Office of Basic Energy Sciences, Energy Frontier Research Center (DESC0001015)
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