Supermolecules Containing a Tetrahedral Core: A New Class of Liquid‐Crystalline Siloxanes
- 1 May 1996
- journal article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 129 (5), 521-525
- https://doi.org/10.1002/cber.19961290508
Abstract
It is shown that supermolecules with a tetrahedral symmetry and appropriate side‐chains exhibit liquid‐crystalline phase behaviour. The use of an optimised hydrosylation reaction allows for the synthesis of materials that have four mesogenic groups attached to a siloxane core, where the conformation and the configuration are unambiguous. The materials show low glass transition temperatures and, depending on the spacer length, complex liquid‐crystalline morphologies.Keywords
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