Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods
Top Cited Papers
- 26 May 2010
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 46 (26), 4668-4679
- https://doi.org/10.1039/c0cc00563k
Abstract
The glycosyl N-phenyltrifluoroacetimidates (PTFAI) have within the last ten years been applied in the synthesis of a wide variety of the oligosaccharides and glycoconjugates. Especially, these donors are found advantageous in glycosidic coupling with ‘arming’ sugar donors, ketose donors, and with less nucleophilic acceptors. A comprehensive review of the PTFAI donors is provided in a hope to reflect from a particular angle the current status and future trend of the glycosylation chemistry.Keywords
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