Controlled Synthesis of Topological Insulator Nanoplate Arrays on Mica

Abstract

The orientation- and position-controlled synthesis of single-crystal topological insulator (Bi₂Se₃ and Bi₂Te₃) nanoplate arrays on mica substrates was achieved using van der Waals epitaxy. Individual ultrathin nanoplates with the lateral dimension up to ∼0.1 mm or uniform thickness down to 1–2 nm were produced. Single-Dirac-cone surface states of nanoplate aggregates were confirmed by angle-resolved photoemission spectroscopy measurements. The large-grain-size, single-crystal nanoplate arrays grown on mica can act as facile platforms for a combination of spectroscopy and in situ transport measurements, which may open up new avenues for studying exotic physical phenomena, surface chemical reactions, and modification in topological insulators.